This excerpt from the Responsorial Psalm for the Mass from Tuesday of the Fifth Week of Lent is an excellent prayer of distress in times of pain:

Psalm 102:2-3: “O LORD, hear my prayer,
and let my cry come to you.
Hide not your face from me
in the day of my distress.
Incline your ear to me;
in the day when I call, answer me speedily.”

(Via USCCB.)

It seems that many of the Psalms picked for the season of Lent recognize the pain and suffering that people find themselves in. Most often it is caused by sin, either the sufferer’s actions or another’s.

Nevertheless, we are being constantly reminded by the Church of the healing and forgiving nature of God.

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